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The infrared (3200 to 400 cm−1) spectra of gaseous and solid and Raman (3200 to 20 cm−1) spectra of liquid and solid ethyl chlorosilane-Si-d2, CH3CH2SiD2Cl, have been recorded. Both the gauche and trans conformers have been identified in the fluid phases, but only the gauche conformer remains in the solid phase. Variable temperature (−105 to −150°C) studies of the infrared spectra of CH3CH2SiH2Cl...
The infrared (3200 to 400 cm−1) and Raman (3200 to 20 cm−1) spectra of gaseous and solid ethylsilane, CH3CH2SiH3, have been recorded. Additionally, the Raman spectrum of the liquid has been obtained with quantitative depolarization values. The SiH3 torsional mode has been observed as sum and difference bands with the silicon-hydrogen stretching vibration. Utilizing the torsional fundamental frequency...
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