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Dominoreaktionen. In der Zuschrift auf S. 3788 ff. präsentieren M.‐H. Zeng et al. die Synthese eines freien Kohlenstoffradikals durch die Dominoreaktion eines primären Amins mit FeCl3⋅6 H2O in Methanol unter Solvothermalbedingungen.
A new free carbon radical was obtained in a microwave‐assisted solvothermal reaction of the primary amine (1‐methyl‐1H‐benzo[d]imidazol‐2‐yl)methanamine with FeCl3⋅6 H2O in methanol at 140 °C. Through a combination of crystallography and electrospray ionization mass spectrometry, the reaction process was studied. The longest domino reaction includes 14 steps and forms up to 12 new covalent bonds (9...
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