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Die Reaktionen, die D. J. H. Emslie et al. in ihrer Zuschrift auf S. 6319 ff. vorstellen, starten bei Mangan und Wasserstoff und führen nacheinander Silicium und Kohlenstoff ein, bereitgestellt von dem im Vordergrund gezeigten Inukshuk, einem von den Bewohnern der arktischen Regionen Nordkanadas genutzten Steinwegweiser. Im Hintergrund erklimmen zwei Silylenhydrid‐Moleküle den Gipfel der “Hounds Tooth”...
Reaction of the ethylene hydride complex trans‐[(dmpe)2MnH(C2H4)] (1) with Et2SiH2 at 20 °C afforded the silylene hydride [(dmpe)2MnH(=SiEt2)] (2 a) as the trans‐isomer. By contrast, reaction of 1 with Ph2SiH2 at 60 °C afforded [(dmpe)2MnH(=SiPh2)] (2 b) as a mixture of the cis (major) and trans (minor) isomers, featuring a Mn‐H‐Si interaction in the former. The reaction to form 2 b also yielded [(dmpe)...
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