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A novel inclusion complex H2O@Q[5]K22+@Q[10]Cl2(HCl)(H2O)37 was synthesized via a self-produced intermediate template route. The X-ray crystallography shows two potassium cations coordinated to each portal of Q[5] to form closed molecular capsule, in which a water molecule was encapsulated. Interestingly, the closed molecular capsule is trapped in the cavity of a bigger macrocycle Q[10] and the inclusion...
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