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The shock tube technique was used to study the high temperature thermal decomposition of methylformate (MF) and methylacetate (MA). The formation of H-atoms was measured behind reflected shock waves by using atomic resonance absorption spectrometry (ARAS). The experiments span a T-range of 1194–1371K at pressures ∼0.5atm. The H-atom profiles were simulated using a detailed chemical kinetic mechanism...
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