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Additive-assisted non-thermal phase separation of P3HT and PCBM was studied using nitrile solvents that have low boiling points. 10volume% of acetonitrile (ACN) or valeronitrile (VN) was added to the P3HT:PCBM blend chlorobezene solution. The P3HT:PCBM bulk heterojunction layer prepared without nitrile solvents showed a power conversion efficiency (PCE) of 0.75%. The ACN addition to the blend solution...
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