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We investigated the electronic structure and chemical bonding of the B3−, Al3−, and Ga3− anions, and the gas phase NaB3, NaAl3, and NaGa3 molecules. We found that the ground state of the neutral gas phase salts contains an equilateral triangular anion interacting with a Na+ cation. The B3−, Al3−, and Ga3− anions possess two delocalized π electrons and are found to be aromatic. The triangular...
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