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Silver service: Two simple compounds, H2O⋅⋅⋅AgCl and H2S⋅⋅⋅AgCl (see picture), formed by interaction of either H2O or H2S with AgCl, are detected by rotational spectroscopy. AgCl is produced by laser ablation of silver in the presence of CCl4 and then picks up H2O or H2S. H2O⋅⋅⋅AgCl is isomorphic with its hydrogen‐ and halogen‐bonded analogues H2O⋅⋅⋅HCl and H2O⋅⋅⋅ClF, while H2S⋅⋅⋅AgCl is similarly...
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