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Oxy-fuel combustion is usually performed in pf reactors under an enriched O2 atmosphere of CO2 to obtain a high CO2 content in the flue gases. The effect of the differences in thermal properties of N2 (conventional air combustion) and CO2 (oxy-fuel combustion) on the devolatilization process needs to be evaluated. The morphology and reactivity of biomass chars obtained by devolatilization in an EFR...
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