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The interactions of hydrogen chloride (HCl) with ultrathin (10-100 monolayers thick) films of ice between 120 and 180 K were studied using temperature programmed desorption (TPD) and Fourier transform infrared reflection absorption spectroscopy (FTIRAS). HCl is initially absorbed by ice at 120 K to form the stoichiometrically fixed hexahydrate phase, HCl 6H 2 O. Infrared spectroscopic...
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