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Infrared data in the gas phase are reported for SiH 2 Br 2 , SiD 2 Br 2 and SiHDBr 2 . Quantum mechanical (QM) calculations of geometry, force field and electrical properties have been carried out for dibromosilane and silane using the 6-31G** basis set at SCF, MP2 and B3LYP levels. In the gas phase, the A 2 torsional mode is calculated to lie at 690+/-1...
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