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Mass spectrometry and quantum chemical studies of the reaction of divinyl telluride with diphenylphosphine sulfide have been carried out. Reaction proceeds under radical initiation (AIBN, 63–68 °С, 2.5 h, THF, reactants molar ratio = 1:1) to afford the anti-Markovnikov monoadduct 1 and diadduct 2 in 67 and 23% yield, respectively. The former easily decomposes to give vinyldiphenylphosphine sulfide...
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