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A new type of chemistry of carbon disulfide proceeding by way of nucleophilic attack of tris(trimethylsilyl)methyllithium (TsiLi) at carbon of carbon disulfide is reported. The treatment of TsiLi and CS 2 with some symmetrical and unsymmetrical benzyl halides has yielded novel multifunctional compounds with SiMe 3 , SH and CS groups. The obtained compounds (mercapto-silyl-thiones)...
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