To settle the hydrogen adsorption sites on buckybowl C 36 H 12 , which is picked up from zeolite-templated carbon (ZTC), we have performed path integral molecular dynamics (PIMD) simulation including thermal and nuclear quantum fluctuations under semi-empirical PM3 method. In the static PM3 calculation and classical simulation the five stable adsorption sites of hydrogen atom are optimized inside a buckybowl C 36 H 12 , which are labeled as α-, β 1 -, β 2 -, γ-, and δ-carbons from edge to innermost carbon. In PIMD simulation, meanwhile, stable adsorption site is not appeared on δ-carbon, but on only α-, β 1 -, β 2 -, and γ-carbons. This result is due to the fact that the adsorbed hydrogen atom can easily go over the barrier for hydrogen transferring from δ- to β 1 -carbons by thermal and nuclear quantum fluctuations. The thermal and nuclear quantum effects are key role to settle the hydrogen adsorption sites on carbon materials.