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The structure, thermochemistry, isomerization and dissociation of the CH 2 BH 2 and CH 3 BH radicals, cations and anions have been explored with a wide range of ab initio levels of computational theory and their formation has been probed by tandem mass spectrometry and RRKM kinetic theory. Calculations predict that CH2BH2⌉+ is not an equilibrium structure on the potential energy...
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