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For the reaction of 2,4-dimethylpentane or 2,4,6-trimethylheptane with t-butoxyl radicals – modelling the controlled-rheology peroxide degradation of polypropylene – only tertiary and primary radicals, with few or no secondary radicals have been identified by some authors. This is in disagreement with what is expected from the C–H bond strength involved in the formation of tertiary and primary radicals...
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