3e,4,5,6e,7,8-Hexahydro[2.2]paracyclophane (11) was prepared through a coupling reaction to form dithiacyclophane, oxidation to yield the sulfone followed by the pyrolysis. It is noteworthy that the methine hydrogen in the rigid structures 5 and 11 toward to the center of the benzene ring leading to high field shifts resonance appear at δ -0.72 and -2.32 -2.41.