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This paper presents the first results of an investigation carried out by the authors on the potentialities of biodiesel as an alternative fuel based on strategic considerations and field experiences in boilers and diesel engines.The operation of a biodiesel fuelled boiler has been checked for some months. The engines have been bench-tested and then installed on urban buses for normal operation. Distances,...
This paper presents the impact of oxygen and nitrogen compounds on the lubrication properties of low sulfur diesel fuels. It discusses the most recent results, concerning the influence of adding low amounts of 4 specific types of biodiesel, 5 aliphatic amines, 2 tertiarty amides, 10 mono-carboxylic acid esters, 3 acetoacetates and 7 esters of di-carboxylic acids on the tribological behaviour of the...
Presence of fully converted monoalkyl esters is the major requirement in quality biodiesel. Due to high associated costs with testing and widespread production of biodiesel not only in commercial scale but also in small scale, there is a high propensity of substandard biodiesel entering the market and being used in compression ignition engines. Due to this reason, it is important to understand how...
The effects of biodiesel (rapeseed methyl ester, RME) and different diesel/RME blends on the diesel engine NO x emissions, smoke, fuel consumption, engine efficiency, cylinder pressure and net heat release rate are analysed and presented. The combustion of RME as pure fuel or blended with diesel in an unmodified engine results in advanced combustion, reduced ignition delay and increased heat...
Many performance and emission tests have been carried out in reciprocating diesel engines that use biodiesel fuel over the past years and very few in gas turbine engines. This work aims at assessing the thermal performance and emissions at full and partial loads of a 30kW diesel micro-turbine engine fed with diesel, biodiesel and their blends as fuel. A cycle simulation was performed using the Gate...
This paper documents the application of exhaust gas fuel reforming of two alternative fuels, biodiesel and bioethanol, in internal combustion engines. The exhaust gas fuel reforming process is a method of on-board production of hydrogen-rich gas by catalytic reaction of fuel and engine exhaust gas. The benefits of exhaust gas fuel reforming have been demonstrated by adding simulated reformed gas to...
Biodiesel has high potential as a new and renewable energy source in the future, as a substitution fuel for petroleum-derived diesel and can be used in existing diesel engine without modification. Currently, more than 95% of the world biodiesel is produced from edible oil which is easily available on large scale from the agricultural industry. However, continuous and large-scale production of biodiesel...
This paper presents the initial results of an experimental investigation of regulated and unregulated emissions of a boiler fueled with biodiesel and heating oil. In particular CO, SO 2 , NO x , particulate matter (PM), Polycyclic Aromatic Hydrocarbons (PAH), Volatile Organic Compounds (VOC) and aldehydes emissions were examined. When using biodiesel, a strong reduction in CO and PM...
The paper assesses the life cycle of biodiesel from used cooking oil (UCO). Such life cycle involves 4 stages: 1) collection, 2) pre-treatment, 3) delivery and 4) transesterification of UCO. Generally, UCO is collected from restaurants, food industries and recycling centres by authorised companies. Then, UCO is pre-treated to remove solid particles and water to increase its quality. After that, it...
Biodiesel is receiving increasing attention as a partial substitute for home heating oil. The properties that make it a suitable fuel for use in diesel engines also make it suitable for heating systems using pressure jet burner technology. In the UK, however, there are a significant number of vaporising burners whose suitability for operation with biodiesel has not been properly studied. The purpose...
Biodiesel, as an alternative fuel is steadily gaining attention to replace petroleum diesel partially or completely. The tribological performance of biodiesel is crucial for its application in automobiles. In the present study, effect of temperature on the tribological performance of palm biodiesel was investigated by using four ball wear machine. Tests were conducted at temperatures 30, 45, 60 and...
Among the alternative fuels, biodiesel and its blends are considered suitable and the most promising fuel for diesel engine. The properties of biodiesel are found similar to that of diesel. Many researchers have experimentally evaluated the performance characteristics of conventional diesel engines fuelled by biodiesel and its blends. However, experiments require enormous effort, money and time. Hence,...
Advances in biodiesel, emulsified diesel and artificial chemical additives are driven by consumer demand to save energy and reduce emissions from diesel engines. However, the effect of emulsified bio-solution/palm-biodiesel/diesel blends in diesel engines has not been assessed. Experimental results in this work demonstrate that the emulsified bio-solution/palm-biodiesel/diesel blends have the advantage...
Various biofuels, including bioethanol and biodiesel are technologically being considered replacements for fossil fuels, such as the conventional gasoline and diesel. This paper aims to measure whether economic substitutability can be generated during periods of higher and/or lower prices of crude oil. The empirical results of the bivariate EGARCH model prove that this substitutive effect was occurred...
When evaluating the production of renewable energies such as biofuels, it is necessary to include in the assessment the resource inputs, capital, labor investment and environmental remediation costs. Extended Exergy Accounting (EEA) is a system analysis method that calculates, on the basis of detailed mass and exergy balances, the total amount of primary exergy resources necessary to obtain a product...
In this paper, parameters affecting castor oil transesterification reaction were investigated. Applying four basic catalysts including NaOCH 3 , NaOH, KOCH 3 and KOH the best one with maximum biodiesel yield was identified. Using Taguchi method consisting four parameters and three levels, the best experimental conditions were determined. Reaction temperature (25, 65 and 80°C), mixing...
High heating value (HHV) is an important property which characterises the energy content of a fuel such as solid, liquid and gaseous fuels. The previous assertion is particularly important for vegetable oils and biodiesels fuels which are expected to replace fossil oils. Estimation of the HHV of vegetable oils and biodiesels by using their fatty acid composition is the aim of this paper. The comparison...
This study investigates the impact of various synthetic phenolic antioxidants on the oxidation stability of biodiesel blends with the employment of the modified Rancimat method. The experimental results revealed that an improvement in oxidation stability could be achieved with all antioxidants tested. Butylated hydroxytoluene (BHT) and butylated hydroxyanisol (BHA) displayed the lowest effectiveness...
The major obstacle to biodiesel commercialization is the high cost of raw materials. Biodiesel from waste cooking oil is an economical source and thus an effective strategy for reducing the raw material cost. Using waste cooking oil also solves the problem of waste oil disposal. This study investigated the emissions of polycyclic aromatic hydrocarbons (PAHs), carcinogenic potencies and regulated matters,...
In the present study, copper vanadium phosphate (CuVOP) with three-dimensional network structure was synthesized by hydrothermal method, and was characterized by Infrared spectrum (IR), elemental analysis (EA), EDXRF (energy dispersive X ray fluorescence) etc. Moreover, soybean oil was used as feedstock for producing biodiesel, and biodiesel was produced by CuVOP-catalyzed transesterification process...
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