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Biofuel development has gained the attention of researchers in recent years owing to the rate of depletion of fossil fuels. Several processes are currently employed in the conventional production of different biofuels: the production of biodiesel is catalytically performed either through the transesterification of triglycerides using alcohol or the deoxygenative ecofining of triglycerides in a non-alcohol...
Methanol production process configurations based on renewable energy sources have been designed. The processes were analyzed in the thermodynamic process simulation tool DNA. The syngas used for the catalytic methanol production was produced by gasification of biomass, electrolysis of water, CO 2 from post-combustion capture and autothermal reforming of natural gas or biogas. Underground gas...
Two models of a dimethyl ether (DME) fuel production plant were designed and analyzed in DNA and Aspen Plus. The plants produce DME by either recycle (RC) or once through (OT) catalytic conversion of a syngas generated by gasification of torrefied woody biomass. Torrefication is a mild pyrolysis process that takes place at 200–300°C. Torrefied biomass has properties similar to coal, which enables...
An experimental study has been carried to use raw Algae oil and its methyl esters in an indirect injection diesel engine. Effects of engine speed, engine load output, injection timing of the algae biofuel and engine compression ratio on the engine output torque, combustion noise (maximum pressure rise rate), maximum pressure and maximum heat release rate have been studied. Raw oil extracted from microalgae...
This paper presents the outcomes of a questionnaire survey to ascertain the perspectives of local communities on the proposal to construct a large-scale biodiesel production facility in the Eastern Cape Province of South Africa, with feedstock supply to the production facility from the former communal homelands of the Province. A total of 303 questionnaires were administered through interactions with...
In this study, regulated and unregulated exhaust emissions with petroleum diesel fuel and Jatropha-based biodiesel blends at proportions of 5%, 10%, 20%, 50% and 100% (v/v) have been investigated. This study examines four regulated emissions: nitrogen oxide, carbon monoxide, unburned hydrocarbon and smoke, and four typical unregulated emissions: formaldehyde, acetaldehyde, acetone and toluene. The...
Due to growing environmental concerns and diminishing petroleum reserves, a wide range of oxygenated species has been proposed as possible substitutes to fossil fuels: alcohols, methyl esters, acyclic and cyclic ethers. After a short review the major detailed kinetic models already proposed in the literature for the combustion of these molecules, the specific classes of reactions considered for modeling...
The present work aims to produce biofuel from fish oil industrial residue and to test the biofuel in diesel engine. A 4.5 kW at 1500 rpm single cylinder air cooled direct injection diesel engine was used for the present experimental work. The experimental results show that the brake thermal efficiency marginally increases with biofuel from 29.98% (neat diesel) to the maximum of 32.4% with biofuel...
Biofuel is a prominent alternative fuel because of its environmental benefits and similar physiochemical properties to diesel fuel. This study investigated the impact of high quality refined, bleached and deodorized (RBD) coconut oil blends and fuel throttle setting on performance and exhaust emissions of diesel engine. The criteria regulated emissions and particulate-phase polycyclic aromatic hydrocarbons...
The aim of this work is to evaluate some production processes of biomass-derived fuels by introducing an exergo-environmental indicator called the Renewability Performance Indicator (λ). This study clearly demonstrates that not all biofuel production processes are sustainable. According to this evaluation methodology, ethanol and sugar production from sugarcane, and ethanol production from amilaceous...
This paper describes the use of bio-oil derived from the pyrolysis of waste wood in a single cylinder, air cooled, direct injection (DI), diesel engine developing power of 4.4 kW at 1500 rpm used in agricultural and standby applications. The combustion, performance and emission characteristics of the diesel engine fueled with three different emulsions made from wood pyrolysis oil (WPO) and Jatropha...
This paper describes the synthesis of a rubber seed supply network to support the green energy demand in Malaysia. An optimised rubber seed supply network design, which maximises biomass utilisation, secures local biomass supply as well as reduces material loss and emissions resulted from inefficient logistic activities has been carried out. The utilisation of rubber seed oil (RSO) for biofuel production...
A new type of biofuel, pine oil, is introduced in this work for the purpose of fueling diesel engine. The viscosity, boiling point and flash point of the reported oil are lower, when compared to that of diesel. Also, the calorific value of pine oil biofuel is comparable to diesel. As a result, it can be directly used in diesel engine without trans-esterifying it. Pine oil biofuel and their blends...
Biomass-derived platform intermediate furfural and levulinic acid were efficiently hydrogenated to the value-added furfuryl alcohol and promising biofuel γ-valerolactone, respectively, using a noble-metal-free Cu–Cr catalyst, which was facilely and successfully synthesized by a modified co-precipitation method using the cheap metal nitrates. In the first hydrogenation of furfural, 95% yield of furfuryl...
Microbial lipids have the potential to substantially reduce the use of liquid fossil fuels, though one obstacle is the energy costs associated with the extraction and subsequent conversion into a biofuel. Here we report a one-step method to produce FAME (fatty acid methyl esters) from Rhodotorula glutinis by combining lipid extraction in a microwave reactor with acid-catalysed transesterification...
Bimetallic Gold–silver core–shell nanoparticles (Au@Ag NPs) were synthesized at room temperature, where gold nanoparticles (AuNPs) served as seeds for continuous deposition of silver atoms on its surface. The core–shell structure was examined by UV–vis spectroscopy, transmission electron microscopy (TEM) and energy dispersive X-ray (EDX) analysis. The catalytic activity of these nanoparticles toward biodiesel...
Alternative diesel fuels for internal combustion engines have grown significantly in interest in the last decade. This is due to the potential benefits in pollutant emissions and particulate matter reduction. Nevertheless at possible increase in nitrogen oxide (NOx), and almost certainly increase of fuel consumption have been observed.In this paper, mineral diesel and RME (rapeseed methyl ester) fuels...
Integrated and external torrefaction is analyzed and compared via thermodynamic modeling. In this paper, integrated torrefaction is defined as torrefaction integrated with entrained flow gasification. External torrefaction is defined as the decentralized production of torrefied wood pellets and centralized conversion of the pellets by entrained flow gasification. First, the syngas production of the...
The extensive use of fossil fuels is increasingly recognized as unsustainable as a consequence of depletion of supplies and the contribution of these fuels to climate change by GHG (greenhouse gas) emissions into the atmosphere. Microalgae indicate alternative renewable sustainable energy sources as they have a high potential for producing large amounts of biomass which in turn can be used for production...
This study describes algal biofuel production, bioelectricity generation and wastewater treatment using Leptolyngbya sp. JPMTW1 (KF977831). The experiments were conducted in an AMFC (Algal Microbial Fuel Cell) photobioreactor (single-chamber). The pH, EC (electrical conductivity), COD (chemical oxygen demand) and TDS (total dissolved solids) decreased from 8.01 to 7.0, 982 to 854 (mS/cm), 255 to 112...
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