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A transient-state mathematical model for an ethanol basin solar still based on Spalding's work was developed. Driving force B was defined based on the mass balance between the evaporating (S) and condensing (G) surfaces. Mass transfer conductance (g) was obtained from an indoor experiment. Then productivity could be calculated. In order to validate the model an ethanol basin solar still was tested...
Ethanol production from cellulosic sources such as switchgrass (Panicum virgatum L.) requires the use of natural resources, fossil fuels, electricity, and human-derived goods and services. We used emergy accounting to integrate the ultimate amount of environmental, fossil fuel, and human-derived energy required to produce ethanol from switchgrass. Emergy is the total amount of energy of one form required...
Sugarcane is one of the most important industries of the Brazilian economy, and its main products are sugar and ethanol. Most of the industrial plants produce both products in an integrated process, in which the sugarcane bagasse is a by-product that can be used as a fuel in the cogeneration system. The bagasse is used as the only fuel of the plant, supplying all energy required for the process, and...
In this paper a new family of sorbents, specifically designed for ethanol sorption, is presented. The composites were synthesized by a dry impregnation of matrices with an aqueous solution of various salts. The ethanol sorption capacity of the composites, under conditions typical for adsorptive air conditioning cycle, has been measured by using an express method based on the Polanyi principle of temperature...
Tropical countries, such as Brazil and Colombia, have the possibility of using agricultural lands for growing biomass to produce bio-fuels such as biodiesel and ethanol. This study applies an energy analysis to the production process of anhydrous ethanol obtained from the hydrolysis of starch and cellulosic and hemicellulosic material present in the banana fruit and its residual biomass. Four different...
This study discusses the performance and exhaust emissions of a vehicle fueled with low content alcohol (ethanol and methanol) blends and pure gasoline. The vehicle tests were performed at wide-open throttle and at vehicle speeds of 40 km h −1 , 60 km h −1 , 80 km h −1 and 100 km h −1 by using an eddy current chassis dynamometer. The test results obtained with the use...
The combined sugar and ethanol production process from sugar cane is a paradigmatic application for energy integration strategies because of the high number of hot and cold streams involved, the external hot utility requirement at two temperature levels for juice evaporation and crystallization, and the electricity demand for juice extraction by milling. These conditions make it convenient to combine...
Coffee cut-stems (CCS) represent a promising candidate for fuel ethanol production in tropical countries because of their high availability and high biomass yield per hectare. In this work, pretreatment of this agricultural residue with dilute sulfuric acid and liquid hot water (LHW) was integrated in the simulation and economic assessment of the process for fuel ethanol production. High reducing...
The production of ethanol via entrained flow gasification of biomass and subsequent catalytic synthesis is economically assessed by considering current and future scenarios. In the current scenarios, the process plants proposed only make use of available technologies and state-of-the-art mixed alcohol catalysts (Rh–Mn/SiO 2 and KCoMoS 2 catalysts). In the future scenarios, the effects...
Biomass based oxygenated fuels have been identified as possible replacement of fossil fuel due to pollutant emission reduction and decrease in over-reliance on fossil fuel energy. In this study, 4v% water-containing ethanol was mixed with (65–90%) diesel using (5–30%) biodiesel (BD) and 1v% butanol as stabilizer and co-solvent respectively. The fuels were tested against those of biodiesel–diesel fuel...
Energy from sources alternative to fossil fuels is being studied and interest in energy derived from vegetal biomass is increasing. In Brazil - mainly at Sao Paulo State -, sugarcane ethanol is being intensively produced on large-scales, giving rise to social and environmental concerns about its production. If ethanol production systems are to maintain a balance between economic, social and environmental...
Biodiesel fuel is known to improve the properties of alcohol-diesel blends for use in compression ignition engines. In this work the effects on combustion characteristics and emissions of preselected methyl esters (i.e. biodiesel components) have been assessed. The most representative individual fatty acid methyl esters (FAMEs) were added to alcohol blends in order to understand the effect of carbon...
Sugarcane bagasse and trash may be used as feedstock for second generation ethanol production. Production of second generation ethanol integrated with first generation plants processing sugarcane presents several advantages over the stand-alone second generation ethanol production process; however, bagasse is used as fuel to supply the energy demand of the first generation process, so the amount of...
This work presents the simulated equilibrium compositions of ethanol steam reforming (SR), partial oxidation (POX) and auto-thermal reforming (ATR) at a large temperature range, steam-to-ethanol and oxygen-to-ethanol molar ratios. The simulation work shows that the moles of hydrogen yield per mole ethanol are of this order: SR > ATR > POX. The results are compared with other simulation works...
In this study, a new thermochemical route to produce lignocellulosic ethanol based on DME (dimethyl ether) hydrocarbonylation is proposed and economically assessed. The process is designed and evaluated using current kinetic laboratory data for hydrocarbonylation reactions. Only available technologies or those expected to be available in the short term are considered for the process design, which...
In this paper an exergy analysis of thermochemical ethanol production from biomass is presented. This process combines a steam-blown indirect biomass gasification of woody feedstock, with a subsequent conversion of produced syngas into ethanol. The production process involves several process sections, including biomass drying and gasification, syngas cleaning, reforming, conditioning, and compression,...
A conceptual biorefinery, based on repurposing a kraft pulp mill, has been studied. In the process an alkaline pre-treatment unit separates the incoming wood raw-material to a cellulose-rich pulp and a residue liquor containing dissolved lignin. The pulp is sent to an ethanol line, while the liquor is gasified and refined to dimethyl ether. The concept has been designed and assessed from an energy...
The objective of this study is to estimate the energetic yields of a combined ethanol and biogas production from three different sorghum varieties, and to compare them to a similar estimate for maize in order to demonstrate the suitability of sorghum as an alternative biomass source. The sorghum varieties “SG1” (Sugargraze I) and “SG2” (Sugargraze II), which produce fermentable sugars, as well as...
This study carried out an exergetic analysis of a proposed ethanol production scheme in which a new process – enzymatic hydrolysis of sugarcane bagasse – is integrated into the conventional process. Seven cases were evaluated, among them a conventional ethanol production plant without hydrolysis, a conventional plant combined with hydrolysis and hydrolysate concentration by evaporation, and a conventional...
Limited crude oil resources and growing environmental awareness have raised a huge led to a huge motivation to seek new fuel alternatives for combustion engines. In this study the goal was to research the potential of ethanol as a compression ignition engine fuel utilizing dual-fuel combustion technology.In the studied DF (dual-fuel) concept, the primary fuel is injected into the intake manifold and...
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