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The Resonance-enhanced two-photon ionization (R2PI) and Mass-analyzed threshold ionization (MATI) spectra of 3-Chloro-N-methylaniline (3ClNMA) were recorded in detail. The experimental and calculated results revealed that cis and trans 3ClNMA are the only two stable conformers for each of the S0, S1 and D0 states. The first electronic excitation energies (E1s) of cis and trans 35Cl-3ClNMA were measured...
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