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Amounts between 2.5 and 5.9% of HBr, HCl and Cl 2 were added to fullerene forming benzene/oxygen/argon flat-flames burning at 75 mbar in an attempt to affect halogen substitutions in the carbon framework. The inhibition effect of HBr dramatically reduced the yield of fullerene, while it stayed in the same order of magnitude after addition of HCl or Cl 2 . No formation of halogenated...
In situ reaction kinetics of bromine intercalation in carbon fibers have been followed by measuring changes in their electrical resistivity during an intercalation and de-intercalation cycle. The study suggests that for well-graphitized P-55(HTT 3000°C) and P-120 carbon fibers the reaction starts instantaneously and most of the charge transfer takes place within the first ten minutes with only 6%...
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