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The vacuum UV photoabsorption spectrum of CH 3 Br has been recorded between 6 and 25eV. A large number of vibronic bands are observed. They were partly ascribed to vibrationless Rydberg transitions. In the high photon energy range of 12–25eV, very weak diffuse bands are mostly assigned to transitions from the 3a 1 , 1e and (2a 1 +1a 1 ) to 3s orbitals. In the 6–12eV...
The fine structure of the vacuum UV photoabsorption spectrum of CH 3 Br and CD 3 Br has been analyzed in the 6.9–10.2 eV photon energy range. A large number of lines have been observed, classified and assigned to the vibrational excitation accompanying a series of Rydberg transitions. The effects of the Jahn–Teller distortion and of the spin–orbit splitting of the ground electronic...
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