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A rovibrational collisional coarse-grain model has been developed to reduce a detailed mechanism for the internal energy excitation and dissociation processes behind a strong shockwave in a nitrogen flow. The rovibrational energy levels of the electronic ground state of the nitrogen molecule were lumped into a smaller number of bins. The reaction rate coefficients of an ab initio database developed...
The effects of molecular rotation on the dynamics of high-temperature nonequilibrium flows is investigated in this work, with an application to nitrogen shocked flows. The overall manifold of rovibrational levels for the ground electronic state of N 2 is firstly obtained through the solution of the radial Schrödinger equation over a high-fidelity potential curve. The obtained solutions predict...
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