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The vibrational spectra of the NH stretching vibrations of aniline-alkene cluster cations have been measured using infrared depletion method. Aniline-ethene cation showed three strong absorption bands at 3448, 3314 and 3220cm -1 . The comparison with MO calculation has shown that the main intermolecular interaction is the NH-π type hydrogen bond between one of the NH bonds of aniline...
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