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The application of fs time resolved infrared, TRIR spectroscopy to complexes of the form M2L4, M2L3L1 and M2L2L21 where M=Mo or W and L or L1=a carboxylate or amidinate has allowed the nature of 1MLCT S1 states to be probed with respect to the location of charge on the ligands. The 3MLCT states, which are formed by intersystem crossing, have similarly been probed in a few instances where M=W but for...
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