As dimension shrinks the volume percent occupied by conventional barrier and liner increases and line resistance (Rs) and via resistance (Rc) increases dramatically. An ultrathin ALD MnN barrier is being evaluated as a single layer barrier for resistance reduction in small structures. >20% and >80% Rs and Rc reduction was demonstrated, while 4× better mean time to failure (MTTF) on the time dependent dielectric breakdown (TDDB) was achieved comparing to conventional barrier/liner. ALD MnN is a potential barrier candidate for future interconnects technology.