Monatshefte für Chemie - Chemical Monthly

Items from 1 to 20 out of 4,607 results

article

Erratum

Monatshefte für Chemie - Chemical Monthly > 1997 > 128 > 1 > 103-103

article

Synthesis and Stereochemistry of Some New Trispiro-1,3-dioxaneswith Axial and Helical Chirality

Ion Grosu, Sorin Mager, Gerard Plé, Istvan Turos, more

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 59-68

Summary. The stereoisomerism of some trispiro-1,3-dioxanes obtained from substituted cyclohexanones and pentaerithrytol is discussed considering the possible trispiro-6,9-syn-9,12-syn, trispiro-6,9-syn-9,12-anti, and trispiro-6,9-anti-9,12-anti structures of the spiro skeleton and the characteristic axial and helical chirality of spiranes with six-membered rings. The influence of the presence of...

article

Synthesis of 3′-Azido, 2′,3′-Didehydro, and 3′,4′-Didehydro Nucleosides from 5-Alkoxymethyluracils

Ahmed E.-S. Abdel-Megied, Erik B. Pedersen, Claus Nielsen

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 99-109

Summary. Reaction of methyl 5-tert-butyldiphenylsilyl-2,3-dideoxy-3-iodo-D-threo-pentofuranoside (3) with silylated 5-alkoxymethyluracils 2a–c using trimethylsilyl trifluoromethanesulfonate as a catalyst afforded the α nucleosides 4a–c and the β nucleosides 5a–c. The corresponding 3′,4′- and 4′,5′-didehydro nucleosides 6–9 were prepared in an elimination reaction by treating the iodo nucleosides...

article

Benzoylation at the meso Position of a Zinc(II) Deuteroporphyrin

Jordi Vázquez, Maria M. González, Cristina Martí, Santi Nonell, more

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 69-79

Summary. By short treatment of zinc(II) deuteroporphyrin-IX dimethyl ester with benzoic anhydride/SnCl₄, a mixture of benzoylated derivatives was obtained from which a tribenzoyl derivative with benzoyl groups at the 2, 4, and γ-meso positions could be isolated in low yield. Except for the known Vilsmeier formylation, this constitutes the first example of a Friedel-Crafts acylation taking place at...

article

Use of Quinizarin as a Spectrophotometric Reagent for MgO Content Analysis of Portland Cement and Cement Clinker

H. Sedaira, K. A. Idriss, M. M. Seleim, M. S. Abdel-Aziz

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 49-58

Summary.A new direct spectrophotometric method for the determination of magnesium oxide in Portland cement and cement clinker is proposed. The method is based on a reaction with quinizarin (QUIN, 1,4-dihydroxyanthraquinone) in ethanol-water (50% v/v) solution at pH=9.510.3. Under optimum conditions, the determination of 0.53.9gml1 of magnesium is possible. The method is rapid and selective and possesses...

article

Reaction of 1-Oxa-4-aza-1,3-butadienes with Ketenes: Synthesis of Functionalized β-Lactams

Krystyna Bogdanowicz-Szwed, Malgorzata Krasodomska

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 81-87

Summary. The reaction of phenylimines derived from β-phenyl-α,β-diketopropionic acid ester (1a) β-phenyl-α,β-diketopropionic acid morpholide (1d), and α,β-diketobutyric acid morpholide (1c) with ketenes 2 in the presence of triethylamine yielded a mixture of diastereoisomeric azetidinones 3 and 4. The reaction of 3e with sodium borohydride involved the reduction of the benzoyl moiety affording hydroxy...

article

Synthesis and Characterization of a Crown Ether Substitued Salicylaldimine^a and its Complexes with Copper(II), Cobalt(II), Nickel(II), and Uranyl(VI)

Ulvi Avcıata, Nebahat Demirhan, Ahmet Gül

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 9-18

Summary. 4′-(ω-Salicylaldiminoacetyl)benzo(15-crown-5) (LH) has been synthesized from 4′-(ω-aminoacetyl)benzo(15-crown-5) and salicylaldehyde. Complexes of this Schiff base with copper(II), nickel(II), cobalt(II), and uranyl(VI) have been prepared from the corresponding metal acetates and chlorides. Insertion of sodium ions into the crown ether-moiety has been accomplished by refluxing LH with sodium...

article

Spectrophotometric Investigation of the Pd(II)-Quercetin Complex in 50% Ethanol

Vesna Kunti, Slavica Blagojevi, Duan Maleev, Zorica Radovi, more

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 41-48

Summary.Composition and stability constant of the Pd(II)-quercetin complex were determined by suitable spectrophotometric methods and pH-metric measurements in 50% Ethanol. It was found that the Pd2+ ion and quercetin form a 1:1 complex in which Pd2+ is linked to quercetin through the carbonyl and the 3-hydroxyl group. The stability constant log1 ranged from 6.05 at pH=5.00 to 4.96 at pH=6.50. The...

article

Benzoylation at the meso Position of a Zinc(II) Deuteroporphyrin

Jordi Vzquez, Maria M. Gonzlez, Cristina Mart, Santi Nonell, more

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 69-79

Summary.By short treatment of zinc(II) deuteroporphyrin-IX dimethyl ester with benzoic anhydride/SnCl4, a mixture of benzoylated derivatives was obtained from which a tribenzoyl derivative with benzoyl groups at the 2, 4, and -meso positions could be isolated in low yield. Except for the known Vilsmeier formylation, this constitutes the first example of a Friedel-Crafts acylation taking place at the...

article

Spectrophotometric Investigation of the Pd(II)-Quercetin Complex in 50% Ethanol

Vesna Kuntić, Slavica Blagojević, Dušan Malešev, Zorica Radović, more

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 41-48

Summary. Composition and stability constant of the Pd(II)-quercetin complex were determined by suitable spectrophotometric methods and pH-metric measurements in 50% Ethanol. It was found that the Pd²⁺ ion and quercetin form a 1:1 complex in which Pd²⁺ is linked to quercetin through the carbonyl and the 3-hydroxyl group. The stability constant log β₁ ranged from 6.05 at pH=5.00 to 4.96 at pH=6.50...

article

Synthesis and Stereochemistry of Some New Trispiro-1,3-dioxaneswith Axial and Helical Chirality

Ion Grosu, Sorin Mager, Gerard Pl, Istvan Turos, more

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 59-68

Summary.The stereoisomerism of some trispiro-1,3-dioxanes obtained from substituted cyclohexanones and pentaerithrytol is discussed considering the possible trispiro-6,9-syn-9,12-syn, trispiro-6,9-syn-9,12-anti, and trispiro-6,9-anti-9,12-anti structures of the spiro skeleton and the characteristic axial and helical chirality of spiranes with six-membered rings. The influence of the presence of chiral...

article

Structural Studies of Cu(II) Chelates with Some Arylidene Derivatives of Benzilic Hydrazide

Y. M. Issa, R. M. Issa, S. A. Abdel-Latif, H. A. Abdel-Salam

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 19-29

Summary.The Cu(II) chelates of some new arylidene derivatives of benzilic hydrazide have been synthesized and were characterized by elemental and thermal analyses, as well as by IR, UV/Vis, ESR, and X-ray spectroscopy. The data revealed the formation of tetrahedral 1:1 (L:M) and square planar 2:1 and 1:2 complexes. In the 1:1 complexes, the organic compounds behave as dibasic tridentate ligands towards...

article

Synthesis of 3-Azido, 2,3-Didehydro, and 3,4-Didehydro Nucleosides from 5-Alkoxymethyluracils

Ahmed E.-S. Abdel-Megied, Erik B. Pedersen, Claus Nielsen

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 99-109

Summary.Reaction of methyl 5-tert-butyldiphenylsilyl-2,3-dideoxy-3-iodo-D-threo-pentofuranoside (3) with silylated 5-alkoxymethyluracils 2ac using trimethylsilyl trifluoromethanesulfonate as a catalyst afforded the nucleosides 4ac and the nucleosides 5ac. The corresponding 3,4- and 4,5-didehydro nucleosides 69 were prepared in an elimination reaction by treating the iodo nucleosides 4ac or 5ac with...

article

Use of Quinizarin as a Spectrophotometric Reagent for MgO Content Analysis of Portland Cement and Cement Clinker

H. Sedaira, K. A. Idriss, M. M. Seleim, M. S. Abdel-Aziz

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 49-58

Summary. A new direct spectrophotometric method for the determination of magnesium oxide in Portland cement and cement clinker is proposed. The method is based on a reaction with quinizarin (QUIN, 1,4-dihydroxyanthraquinone) in ethanol-water (50% v/v) solution at pH=9.5–10.3. Under optimum conditions, the determination of 0.5–3.9 μgċml⁻¹ of magnesium is possible. The method is rapid and selective...

article

Reaction of 1-Oxa-4-aza-1,3-butadienes with Ketenes: Synthesis of Functionalized -Lactams

Krystyna Bogdanowicz-Szwed, Malgorzata Krasodomska

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 81-87

Summary.The reaction of phenylimines derived from -phenyl-,-diketopropionic acid ester (1a) -phenyl-,-diketopropionic acid morpholide (1d), and ,-diketobutyric acid morpholide (1c) with ketenes 2 in the presence of triethylamine yielded a mixture of diastereoisomeric azetidinones 3 and 4. The reaction of 3e with sodium borohydride involved the reduction of the benzoyl moiety affording hydroxy derivative...

article

Structural Studies of Cu(II) Chelates with Some Arylidene Derivatives of Benzilic Hydrazide

Y. M. Issa, R. M. Issa, S. A. Abdel-Latif, H. A. Abdel-Salam

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 19-29

Summary. The Cu(II) chelates of some new arylidene derivatives of benzilic hydrazide have been synthesized and were characterized by elemental and thermal analyses, as well as by IR, UV/Vis, ESR, and X-ray spectroscopy. The data revealed the formation of tetrahedral 1:1 (L :M) and square planar 2:1 and 1:2 complexes. In the 1:1 complexes, the organic compounds behave as dibasic tridentate ligands...

article

Crystal Structure and Spectroscopic Behaviour of Oxoetoxo-bis(5,7-dichloro-8-hydroxyquinolinato)vanadium(V)

Ana C. González-Baró, Oscar E. Piro, Beatriz S. Parajón-Costa, Enrique J. Baran, more

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 31-39

Summary. The title compound, a new example of an inorganic ester-like complex, was characterized by spectroscopic and X-ray crystallographic methods. It crystallizes in the triclinic space group P1 (a=9.413(2), b=10.595(3), c=11.783(2) Å, α=103.59(2), β=101.98(2), γ=99.40(2)°, Z=2). The structure was solved employing 2902 independent reflections with I>2σ(I) by direct and Fourier methods and refined...

article

Synthesis and Characterization of Spin-Free [Co2(N,N-Tetra(4-antipyrylmethyl)-1,2-diaminoethane)Cl4]

Mohammed Enamullah, Wolfgang Linert

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 3-7

Summary.The ligand N,N-tetra(4-antipyrylmethyl)-1,2-diaminoethane (TAMEN) coordinates to two Co(II) ions and forms the tetrahedral homodinuclear complex [Co2(TAMEN)Cl4]. In methanol, the complex shows a weak absorbtion spectrum with a maximum at 5150.5nm and a molar absorbtivity of 40.01.0lmol1cdot;cm1. Variable temperature spectra (282 to 323K) show no changes of this band and suggest the absence...

article

Crystal Structure and Spectroscopic Behaviour of Oxoetoxo-bis(5,7-dichloro-8-hydroxyquinolinato)vanadium(V)

Ana C. Gonzlez-Bar, Oscar E. Piro, Beatriz S. Parajn-Costa, Enrique J. Baran, more

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 31-39

Summary.The title compound, a new example of an inorganic ester-like complex, was characterized by spectroscopic and X-ray crystallographic methods. It crystallizes in the triclinic space group P1 (a=9.413(2), b=10.595(3), c=11.783(2), =103.59(2), =101.98(2), =99.40(2), Z=2). The structure was solved employing 2902 independent reflections with I2(I) by direct and Fourier methods and refined by a full-matrix...

article

Synthese und Geruchseigenschaften von Apo- und Homocampholenverbindungen

Cornelia Prehn, Ines Sprung, Katrin Anhalt, Klaus Schulze

Monatshefte für Chemie - Chemical Monthly > 1998 > 129 > 1 > 89-97

Summary.New substances of the brahmanol type with special substitution at the five-membered ring are included in the study of the relationship between structure and odour of sandalwood fragrances. Apobrahmanol compounds 14 and 17 are obtained from myrtenal via apocampholenic aldehyde (12) and exert sandalwood odour. The homobrahmanol derivatives 10 and 11, synthesized from -pinene via fencholenic...

Filter options

FreeMarker template error (HTML_DEBUG mode; use RETHROW in production!)


Java method "org.springframework.web.servlet.support.RequestContext.getMessage(String)" threw an exception when invoked on org.springframework.web.servlet.support.RequestContext object "org.springframework.web.servlet.support.RequestContext@74d63fdf"; see cause exception in the Java stack trace.

----
FTL stack trace ("~" means nesting-related):
	- Failed at: ${springMacroRequestContext.getMessag...  [in template "META-INF/freemarker-templates/spring.ftl" in macro "message" at line 28, column 22]
	- Reached through: @spring.message "portal.searchResult...  [in template "META-INF/freemarker-templates/portal/search/facets.ftl" at line 149, column 33]
----

Java stack trace (for programmers):
----
freemarker.core._TemplateModelException: [... Exception message was already printed; see it above ...]
	at freemarker.ext.beans._MethodUtil.newInvocationTemplateModelException(_MethodUtil.java:289)
	at freemarker.ext.beans._MethodUtil.newInvocationTemplateModelException(_MethodUtil.java:261)
	at freemarker.ext.beans.OverloadedMethodsModel.exec(OverloadedMethodsModel.java:65)
	at freemarker.core.MethodCall._eval(MethodCall.java:65)
	at freemarker.core.Expression.eval(Expression.java:81)
	at freemarker.core.DollarVariable.calculateInterpolatedStringOrMarkup(DollarVariable.java:96)
	at freemarker.core.DollarVariable.accept(DollarVariable.java:59)
	at freemarker.core.Environment.visit(Environment.java:363)
	at freemarker.core.Environment.invoke(Environment.java:715)
	at freemarker.core.UnifiedCall.accept(UnifiedCall.java:83)
	at freemarker.core.Environment.visit(Environment.java:327)
	at freemarker.core.Environment.visit(Environment.java:333)
	at freemarker.core.Environment.visit(Environment.java:369)
	at freemarker.core.IteratorBlock$IterationContext.executedNestedContentForCollOrSeqListing(IteratorBlock.java:316)
	at freemarker.core.IteratorBlock$IterationContext.executeNestedContent(IteratorBlock.java:272)
	at freemarker.core.IteratorBlock$IterationContext.accept(IteratorBlock.java:243)
	at freemarker.core.Environment.visitIteratorBlock(Environment.java:596)
	at freemarker.core.IteratorBlock.acceptWithResult(IteratorBlock.java:108)
	at freemarker.core.IteratorBlock.accept(IteratorBlock.java:94)
	at freemarker.core.Environment.visit(Environment.java:327)
	at freemarker.core.Environment.visit(Environment.java:333)
	at freemarker.core.Environment.visit(Environment.java:333)
	at freemarker.core.Environment.visit(Environment.java:333)
	at freemarker.core.Environment.process(Environment.java:306)
	at freemarker.ext.servlet.FreemarkerServlet.processEnvironment(FreemarkerServlet.java:910)
	at freemarker.ext.servlet.FreemarkerServlet.process(FreemarkerServlet.java:879)
	at freemarker.ext.servlet.FreemarkerServlet.doGet(FreemarkerServlet.java:764)
	at org.apache.tiles.request.freemarker.render.FreemarkerRenderer.render(FreemarkerRenderer.java:73)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:259)
	at org.apache.tiles.template.InsertAttributeModel.renderAttribute(InsertAttributeModel.java:188)
	at org.apache.tiles.template.InsertAttributeModel.execute(InsertAttributeModel.java:132)
	at org.apache.tiles.jsp.taglib.InsertAttributeTag.doTag(InsertAttributeTag.java:299)
	at freemarker.ext.jsp.SimpleTagDirectiveModel.execute(SimpleTagDirectiveModel.java:92)
	at freemarker.core.Environment.visit(Environment.java:427)
	at freemarker.core.UnifiedCall.accept(UnifiedCall.java:101)
	at freemarker.core.Environment.visit(Environment.java:327)
	at freemarker.core.Environment.visit(Environment.java:333)
	at freemarker.core.Environment.process(Environment.java:306)
	at freemarker.ext.servlet.FreemarkerServlet.processEnvironment(FreemarkerServlet.java:910)
	at freemarker.ext.servlet.FreemarkerServlet.process(FreemarkerServlet.java:879)
	at freemarker.ext.servlet.FreemarkerServlet.doGet(FreemarkerServlet.java:764)
	at org.apache.tiles.request.freemarker.render.FreemarkerRenderer.render(FreemarkerRenderer.java:73)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:259)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:397)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:238)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:221)
	at org.apache.tiles.renderer.DefinitionRenderer.render(DefinitionRenderer.java:59)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:259)
	at org.apache.tiles.template.InsertAttributeModel.renderAttribute(InsertAttributeModel.java:188)
	at org.apache.tiles.template.InsertAttributeModel.execute(InsertAttributeModel.java:132)
	at org.apache.tiles.jsp.taglib.InsertAttributeTag.doTag(InsertAttributeTag.java:299)
	at freemarker.ext.jsp.SimpleTagDirectiveModel.execute(SimpleTagDirectiveModel.java:92)
	at freemarker.core.Environment.visit(Environment.java:427)
	at freemarker.core.UnifiedCall.accept(UnifiedCall.java:101)
	at freemarker.core.Environment.visit(Environment.java:327)
	at freemarker.core.Environment.visit(Environment.java:333)
	at freemarker.core.Environment.process(Environment.java:306)
	at freemarker.ext.servlet.FreemarkerServlet.processEnvironment(FreemarkerServlet.java:910)
	at freemarker.ext.servlet.FreemarkerServlet.process(FreemarkerServlet.java:879)
	at freemarker.ext.servlet.FreemarkerServlet.doGet(FreemarkerServlet.java:764)
	at org.apache.tiles.request.freemarker.render.FreemarkerRenderer.render(FreemarkerRenderer.java:73)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:259)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:397)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:238)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:221)
	at org.apache.tiles.renderer.DefinitionRenderer.render(DefinitionRenderer.java:59)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:259)
	at org.apache.tiles.template.InsertAttributeModel.renderAttribute(InsertAttributeModel.java:188)
	at org.apache.tiles.template.InsertAttributeModel.execute(InsertAttributeModel.java:132)
	at org.apache.tiles.jsp.taglib.InsertAttributeTag.doTag(InsertAttributeTag.java:299)
	at freemarker.ext.jsp.SimpleTagDirectiveModel.execute(SimpleTagDirectiveModel.java:92)
	at freemarker.core.Environment.visit(Environment.java:427)
	at freemarker.core.UnifiedCall.accept(UnifiedCall.java:101)
	at freemarker.core.Environment.visit(Environment.java:327)
	at freemarker.core.Environment.visit(Environment.java:333)
	at freemarker.core.Environment.process(Environment.java:306)
	at freemarker.ext.servlet.FreemarkerServlet.processEnvironment(FreemarkerServlet.java:910)
	at freemarker.ext.servlet.FreemarkerServlet.process(FreemarkerServlet.java:879)
	at freemarker.ext.servlet.FreemarkerServlet.doGet(FreemarkerServlet.java:764)
	at org.apache.tiles.request.freemarker.render.FreemarkerRenderer.render(FreemarkerRenderer.java:73)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:259)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:397)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:238)
	at org.apache.tiles.impl.BasicTilesContainer.render(BasicTilesContainer.java:221)
	at org.apache.tiles.renderer.DefinitionRenderer.render(DefinitionRenderer.java:59)
	at org.springframework.web.servlet.view.tiles3.TilesView.renderMergedOutputModel(TilesView.java:132)
	at pl.edu.icm.synat.common.ui.tiles.FreeMarkerAndTilesView.renderMergedOutputModel(FreeMarkerAndTilesView.java:148)
	at org.springframework.web.servlet.view.AbstractView.render(AbstractView.java:303)
	at org.springframework.web.servlet.DispatcherServlet.render(DispatcherServlet.java:1243)
	at org.springframework.web.servlet.DispatcherServlet.processDispatchResult(DispatcherServlet.java:1027)
	at org.springframework.web.servlet.DispatcherServlet.doDispatch(DispatcherServlet.java:971)
	at org.springframework.web.servlet.DispatcherServlet.doService(DispatcherServlet.java:893)
	at org.springframework.web.servlet.FrameworkServlet.processRequest(FrameworkServlet.java:965)
	at org.springframework.web.servlet.FrameworkServlet.doGet(FrameworkServlet.java:856)
	at javax.servlet.http.HttpServlet.service(HttpServlet.java:620)
	at org.springframework.web.servlet.FrameworkServlet.service(FrameworkServlet.java:841)
	at javax.servlet.http.HttpServlet.service(HttpServlet.java:727)
	at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:303)
	at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
	at org.apache.tomcat.websocket.server.WsFilter.doFilter(WsFilter.java:52)
	at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:241)
	at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:316)
	at org.springframework.security.web.access.intercept.FilterSecurityInterceptor.invoke(FilterSecurityInterceptor.java:126)
	at org.springframework.security.web.access.intercept.FilterSecurityInterceptor.doFilter(FilterSecurityInterceptor.java:90)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.access.ExceptionTranslationFilter.doFilter(ExceptionTranslationFilter.java:114)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.session.SessionManagementFilter.doFilter(SessionManagementFilter.java:122)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.authentication.AnonymousAuthenticationFilter.doFilter(AnonymousAuthenticationFilter.java:111)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.authentication.rememberme.RememberMeAuthenticationFilter.doFilter(RememberMeAuthenticationFilter.java:149)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.servletapi.SecurityContextHolderAwareRequestFilter.doFilter(SecurityContextHolderAwareRequestFilter.java:168)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.savedrequest.RequestCacheAwareFilter.doFilter(RequestCacheAwareFilter.java:48)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.FilterChainProxy.doFilterInternal(FilterChainProxy.java:207)
	at org.springframework.security.web.FilterChainProxy.doFilter(FilterChainProxy.java:184)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.authentication.AbstractAuthenticationProcessingFilter.doFilter(AbstractAuthenticationProcessingFilter.java:205)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.jasig.cas.client.session.SingleSignOutFilter.doFilter(SingleSignOutFilter.java:100)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.authentication.AbstractAuthenticationProcessingFilter.doFilter(AbstractAuthenticationProcessingFilter.java:205)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.authentication.logout.LogoutFilter.doFilter(LogoutFilter.java:120)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.authentication.logout.LogoutFilter.doFilter(LogoutFilter.java:120)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.header.HeaderWriterFilter.doFilterInternal(HeaderWriterFilter.java:64)
	at org.springframework.web.filter.OncePerRequestFilter.doFilter(OncePerRequestFilter.java:107)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.context.request.async.WebAsyncManagerIntegrationFilter.doFilterInternal(WebAsyncManagerIntegrationFilter.java:53)
	at org.springframework.web.filter.OncePerRequestFilter.doFilter(OncePerRequestFilter.java:107)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.session.ConcurrentSessionFilter.doFilter(ConcurrentSessionFilter.java:133)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.context.SecurityContextPersistenceFilter.doFilter(SecurityContextPersistenceFilter.java:91)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.access.channel.ChannelProcessingFilter.doFilter(ChannelProcessingFilter.java:152)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.saml.metadata.MetadataGeneratorFilter.doFilter(MetadataGeneratorFilter.java:87)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at pl.edu.icm.synat.portal.web.security.PortalLocaleFilter.doFilterInternal(PortalLocaleFilter.java:51)
	at org.springframework.web.filter.OncePerRequestFilter.doFilter(OncePerRequestFilter.java:107)
	at org.springframework.security.web.FilterChainProxy$VirtualFilterChain.doFilter(FilterChainProxy.java:330)
	at org.springframework.security.web.FilterChainProxy.doFilterInternal(FilterChainProxy.java:213)
	at org.springframework.security.web.FilterChainProxy.doFilter(FilterChainProxy.java:176)
	at org.springframework.web.filter.DelegatingFilterProxy.invokeDelegate(DelegatingFilterProxy.java:344)
	at org.springframework.web.filter.DelegatingFilterProxy.doFilter(DelegatingFilterProxy.java:261)
	at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:241)
	at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
	at ch.qos.logback.classic.helpers.MDCInsertingServletFilter.doFilter(MDCInsertingServletFilter.java:51)
	at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:241)
	at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
	at org.springframework.web.filter.CharacterEncodingFilter.doFilterInternal(CharacterEncodingFilter.java:85)
	at org.springframework.web.filter.OncePerRequestFilter.doFilter(OncePerRequestFilter.java:107)
	at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:241)
	at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
	at pl.edu.icm.synat.portal.web.security.RemoteIpFilter.doFilter(RemoteIpFilter.java:75)
	at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:241)
	at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
	at net.bull.javamelody.MonitoringFilter.doFilter(MonitoringFilter.java:219)
	at net.bull.javamelody.MonitoringFilter.doFilter(MonitoringFilter.java:196)
	at org.apache.catalina.core.ApplicationFilterChain.internalDoFilter(ApplicationFilterChain.java:241)
	at org.apache.catalina.core.ApplicationFilterChain.doFilter(ApplicationFilterChain.java:208)
	at org.apache.catalina.core.StandardWrapperValve.invoke(StandardWrapperValve.java:220)
	at org.apache.catalina.core.StandardContextValve.invoke(StandardContextValve.java:122)
	at org.apache.catalina.authenticator.AuthenticatorBase.invoke(AuthenticatorBase.java:504)
	at org.apache.catalina.core.StandardHostValve.invoke(StandardHostValve.java:170)
	at org.apache.catalina.valves.ErrorReportValve.invoke(ErrorReportValve.java:103)
	at org.apache.catalina.core.StandardEngineValve.invoke(StandardEngineValve.java:116)
	at org.apache.catalina.connector.CoyoteAdapter.service(CoyoteAdapter.java:421)
	at org.apache.coyote.ajp.AjpProcessor.process(AjpProcessor.java:190)
	at org.apache.coyote.AbstractProtocol$AbstractConnectionHandler.process(AbstractProtocol.java:611)
	at org.apache.tomcat.util.net.JIoEndpoint$SocketProcessor.run(JIoEndpoint.java:314)
	at java.util.concurrent.ThreadPoolExecutor.runWorker(ThreadPoolExecutor.java:1142)
	at java.util.concurrent.ThreadPoolExecutor$Worker.run(ThreadPoolExecutor.java:617)
	at org.apache.tomcat.util.threads.TaskThread$WrappingRunnable.run(TaskThread.java:61)
	at java.lang.Thread.run(Thread.java:745)
Caused by: org.springframework.context.NoSuchMessageException: No message found under code 'portal.searchResult.facet.^journalYear^journalVolume' for locale 'en'.
	at org.springframework.context.support.AbstractMessageSource.getMessage(AbstractMessageSource.java:159)
	at org.springframework.context.support.DelegatingMessageSource.getMessage(DelegatingMessageSource.java:66)
	at org.springframework.context.support.AbstractApplicationContext.getMessage(AbstractApplicationContext.java:1129)
	at org.springframework.web.servlet.support.RequestContext.getMessage(RequestContext.java:712)
	at org.springframework.web.servlet.support.RequestContext.getMessage(RequestContext.java:678)
	at sun.reflect.GeneratedMethodAccessor237.invoke(Unknown Source)
	at sun.reflect.DelegatingMethodAccessorImpl.invoke(DelegatingMethodAccessorImpl.java:43)
	at java.lang.reflect.Method.invoke(Method.java:497)
	at freemarker.ext.beans.BeansWrapper.invokeMethod(BeansWrapper.java:1458)
	at freemarker.ext.beans.ReflectionCallableMemberDescriptor.invokeMethod(ReflectionCallableMemberDescriptor.java:56)
	at freemarker.ext.beans.MemberAndArguments.invokeMethod(MemberAndArguments.java:51)
	at freemarker.ext.beans.OverloadedMethodsModel.exec(OverloadedMethodsModel.java:61)
	... 179 more

Financed by the National Centre for Research and Development under grant No. SP/I/1/77065/10 by the strategic scientific research and experimental development program: SYNAT - “Interdisciplinary System for Interactive Scientific and Scientific-Technical Information”.

INFONA - science communication portal

Monatshefte für Chemie - Chemical Monthly

Add recipient

Sending message cancelled

Are you sure you want to cancel sending this message?

Send message

Filter options

Reporting an error / abuse

Sending the report failed

Accessibility options