The three- point bend strength, Young’s modulus, and vibrational damping of a plasma- sprayed molybdenum-coated Ti- 25Al- 10Nb- 3V- lMo intermetallic were measured. The bend strength of the intermetallic samples was significantly reduced as a result of the molybdenum coating. This decrease in the strength was attributed to cracks formed in the molybdenum coating during the plasma spraying process. Experimental measurements done using the piezoelectric ultrasonic composite technique (PUCOT) indicated that the modulus and vibrational damping of the coated samples were significantly higher than for the uncoated substrates. Thermal cycling of the molybdenum- coated intermetallic between 600 °C and room temperature revealed a saturation increase in the modulus with a corresponding decrease in the mechanical damping. This behavior was attributed to crack healing occurring in the molybdenum coating during the thermal cycling process.