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Carbohydrates are the most abundant organic material on Earth and the structural “material of choice” in many living systems. Nevertheless, design and engineering of synthetic carbohydrate materials presently lag behind that for protein and nucleic acids. Bottom‐up engineering of carbohydrate materials demands an atomic‐level understanding of their molecular structures and interactions in condensed...
The precise control over hierarchical self‐assembly of superstructures relying on the elaboration of multiple noncovalent interactions between basic building blocks is both elusive and highly desirable. We herein report a terpyridine‐based metallo‐cage T with a tetrahedral motif and utilized it as an efficient building block for the controlled hierarchical self‐assembly of superstructures in response...
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