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We present a metal docking strategy utilizing the precise spatial arrangement of organic struts as metal chelating sites in a MOF. Pairs of uncoordinated N atoms on adjacent pyrazole dicarboxylate linkers distributed along the rod‐shaped Al–O secondary building units in MOF‐303 [Al(OH)(C5H2O4N2)] were used to chelate CuI and AgI with atomic precision and yield the metalated Cu‐ and Ag‐MOF‐303 compounds...
Die Xenon‐Abtrennung von Krypton durch poröse Adsorbentien ist eine nachhaltige Technologie für die Produktion von kleinvolumigem, aber hochwertigem Edelgas. MOFs sind Adsorbentien, deren Trennleistung durch Abstimmung von Porenmetriken, Funktionalitäten und Gegenionen optimiert werden können. Yue‐Biao Zhang, Omar M. Yaghi und Mitarbeiter beschreiben in ihrer Zuschrift auf S. 3459 eine neue Methode...
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