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Pore‐shape fixing effects (PSFEs) in soft porous crystals are a relatively unexplored area of materials chemistry. We report the PSFE in the prototypical dynamic van der Waals solid p‐tert‐butylcalix[4]arene (TBC4). Starting with the high‐density guest‐free phase, two porous shape‐fixed phases were programmed using the stimuli of CO2 pressure and temperature. A suite of complementary in situ techniques,...
Pore‐shape fixing effects (PSFEs) in soft porous crystals are a relatively unexplored area of materials chemistry. We report the PSFE in the prototypical dynamic van der Waals solid p‐tert‐butylcalix[4]arene (TBC4). Starting with the high‐density guest‐free phase, two porous shape‐fixed phases were programmed using the stimuli of CO2 pressure and temperature. A suite of complementary in situ techniques,...