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Thiomolybdates are molecular molybdenum‐sulfide clusters formed from Mo centers and sulfur‐based ligands. For decades, they have attracted the interest of synthetic chemists due to their unique structures and their relevance in biological systems, e.g., as reactive sites in enzymes. More recently, thiomolybdates are explored from the catalytic point of view and applied as homogeneous and molecular...
Thiomolybdate Clusters
Molecular molybdenum sulfides, or thiomolybdates, are an emerging class of highly active catalysts for the hydrogen evolution reaction. The article number 2305730 by Carsten Streb, Alexey Cherevan, and co‐workers critically assesses the performance of thiomolybdates under homogeneous and heterogenized conditions, and sheds light on the mechanisms which govern photocatalytic...
Surface modification of electrocatalysts to obtain new or improved electrocatalytic performance is currently the main strategy for designing advanced nanocatalysts. In this work, highly dispersed amorphous molybdenum trisulfide‐anchored Platinum nanodendrites (denoted as Pt‐a‐MoS3 NDs) are developed as efficient hydrogen evolution electrocatalysts. The formation mechanism of spontaneous in situ polymerization...