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Converting carbon dioxide (CO2) into fuel and high‐value‐added chemicals is considered a green and effective way to solve global energy and environmental problems. Covalent triazine frameworks (CTFs) are extensively utilized as an emerging catalyst for photo/electrocatalytic CO2 reduction reaction (CO2RR) recently recognized for their distinctive qualities, including excellent thermal and chemical...
Thiomolybdates are molecular molybdenum‐sulfide clusters formed from Mo centers and sulfur‐based ligands. For decades, they have attracted the interest of synthetic chemists due to their unique structures and their relevance in biological systems, e.g., as reactive sites in enzymes. More recently, thiomolybdates are explored from the catalytic point of view and applied as homogeneous and molecular...
Thiomolybdate Clusters
Molecular molybdenum sulfides, or thiomolybdates, are an emerging class of highly active catalysts for the hydrogen evolution reaction. The article number 2305730 by Carsten Streb, Alexey Cherevan, and co‐workers critically assesses the performance of thiomolybdates under homogeneous and heterogenized conditions, and sheds light on the mechanisms which govern photocatalytic...
Metal–organic frameworks (MOFs) and their derivatives have attracted much attention in the field of photo/electrocatalysis owing to their ultrahigh porosity, tunable properties, and superior coordination ability. Regulating the valence electronic structure and coordination environment of MOFs is an effective way to enhance their intrinsic catalytic performance. Rare earth (RE) elements with 4f orbital...