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Consideration of the mechanism of the quasi‐Favorskii rearrangement quickly reveals that there are a number of related reactions, including the benzylic acid rearrangement and the pinacol rearrangement. This chapter focuses on processes that proceed via an anionic tetrahedral intermediate that breaks down via expulsion of some leaving group and concomitant bond migration to generate the product observed...
The multicopper oxidases (MCOs) are a ubiquitous family of proteins that carry out four single‐electron oxidations of substrates coupled to the four‐electron reduction of dioxygen to water. The combination of solution and electrochemical experiments has the potential to enhance our understanding of the MCOs in general and for biofuel cell applications in particular. Ambiguous redox peaks observed...
This chapter contains sections titled:
Solid‐Phase Interaction
The Solid‐Phase Substrate and Attachment of Functional Groups
Reverse‐Phase Ion‐Pairing Separation Mechanism
Ion‐Exchange Separation Mechanism
Chaotropic Denaturing Interaction Mechanism
Hybridization
Gel Filtration
References
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