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The octanol/water partition coefficients (K ow ) for a series of technical toxaphene peaks and congeners (n = 36) and organochlorines (pentachlorobenzene (PClBz), hexachlorobenzene (HClBz), mirex and polychlorinated biphenyl congeners (CB) 105, 153 and 209) were determined using the ''slow-stirring'' technique with two different concentrations at 25 o C. K ow s of...
Ion source temperature, sample amount and the positions of the chlorine atoms attached to the neutral molecule all had profound effects on the appearance of the ECNI mass spectra of a number of synthesized polychloro-n-alkanes (PCAs). Increases in the ion source temperature resulted in a decrease in the abundances of both the [M + Cl] - and [M - Cl] - ions, while the abundances of...
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