Along with economic development and the implementation of large-scale construction activities, human energy demand is also growing, resulting in the use of fossil energy resources can reduce the increasing volume, solar energy as a new, clean and renewable energy sources were widespread concern. And how to combine the solar energy technology to the building is a considering question. This paper firstly described the development of the solar energy photovoltaic's technology and the advantage of BiPV, and further research the application of solar energy photovoltaic's technology on the building surface. The last, it illuminate the combination of building surface and solar energy technology through the analysis of instance. There is a certain meaning for applying the solar energy photovoltaic's technology to building surface.