Free convection heat transfer along an isothermal vertical wavy surface was studied experimentally and numerically. A Mach-Zehnder Interferometer was used in the experiment to determine the local heat transfer coefficients. Experiments were done for three different amplitude–wavelength ratios of α = 0.05, 0.1, 0.2 and the Rayleigh numbers ranging from Ra l = 2.9 × 105 to 5.8 × 105. A finite-volume based code was developed to verify the experimental study and obtain the results for all the amplitude–wavelength ratios between α = 0 to 0.2. It is found that the numerical results agree well with the experimental data. Results indicate that the frequency of the local heat transfer rate is the same as that of the wavy surface. The average heat transfer coefficient decreases as the amplitude–wavelength ratio increases and there is a significant difference between the average heat transfer coefficients of the surface with α = 0.2 and those surfaces with α = 0.05 and 0.1. The experimental data are correlated with a single equation which gives the local Nusselt number along the wavy surface as a function of the amplitude–wavelength ratio and the Rayleigh number.