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Time-resolved UV–vis absorption spectroscopy (TRUVVAS) has been coupled with 248nm laser flash photolysis (LFP) of Cl 2 CO in the presence of CS 2 (and in some cases O 2 , NO or NO 2 ) to generate the CS 2 Cl radical adduct in the gas phase and study the spectroscopy and kinetics of this species. CS 2 Cl is found to possess a strong absorption band at...
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