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Chinese Jiang‐flavor Baijiu is the most widely consumed liquor. Jiang‐flavor Daqu, a fermentation starter, is important sources of key flavors of Jiang‐flavor Baijiu. Some microbes play significant roles in flavor formation of Daqu. In order to clarify the microbial population that promotes the formation of Daqu flavor, we use high throughput sequencing technology combined with headspace solid‐phase...