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UV‐B‐induced corneal damage remains a challenge in clinics, and it is needed to develop novel and effective medicines against UV‐B induced photodamage. 3,4‐Dihydropyrimidine‐2(1H)‐thione derivatives have shown many interesting biological activities, including antibacterial, anti‐inflammatory, antioxidant, etc. In order to find a promising anticorneal photodamage agent, we designed and synthesized...
(−)-Renieramycin G, a marine antitumor natural product, is a typical member of the bis-tetrahydroisoquinoline alkaloid family. In this paper, an efficient protocol of asymmetric total synthesis of its three stereoisomers, (+)-renieramycin G, 11,13-epi-(+)-renieramycin G and 11,13-epi-(−)-renieramycin G was established by the use of a combination of l- and/or d-tyrosine as the starting materials. The...
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