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Narrow disperse core–brush polymer nanoparticles (BP) were synthesized by grafting from photo-induced atom transfer radical polymerization (ATRP) of 2-hydroxyethyl methacrylate (HEMA) from N,N-diethyldithiocarbamate (DC) groups of core–shell particle surface. We constructed colloidal crystals of these particles by depositing on glass substrate. By variation of the particle size, the brilliant color...