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Metal nanoclusters with precisely modulated structures at the nanoscale give us the opportunity to synthesize and investigate 1D nanomaterials at the atomic level. Herein, it realizes selective 1D growth of building block nanocluster “Au13Cd2” into three structurally different nanoclusters: “hand‐in‐hand” (Au13Cd2)2O, “head‐to‐head” Au25, and “shoulder‐to‐shoulder” Au33. Detailed studies further reveals...
Thiolates endow metal nanoclusters with stability while sometimes inhibit the catalytic activity due to the strong M−S interaction (M: metal atom). To improve the catalytic activity and keep the stability to some extent, one strategy is the partial phosphorization of thiolated metal nanoclusters. This is demonstrated by successful partial phosphorization of Au23(SC6H11)16 and by revealing that the...
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