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We report a methodical study about the third order optical nonlinearity of anisotropic growth of ZnO crystals embedded in polymeric matrices and nanowires on the glass substrate with the use of pre-existing textured ZnO, ZnS and TiO 2 seeds using a Z-scan method with Nd:YAG laser (532nm, 7ns, 10Hz). The studies show that the optical nonlinearity of ZnO crystals is highly dependent on the structural...