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Two isostructural heterometallic complexes, {[Dy3Ni3(H2O)3(mpko)9(O2)(NO3)3](ClO4)·3CH3OH·3CH3CN} (1) and {[Gd3Ni3(H2O)3(mpko)9(O2)(NO3)3](NO3)·10.75CH3OH} (2) [mpkoH = 1‐(pyrazin‐2‐yl)ethanone oxime], were solvothermally synthesized by varying lanthanide ions with different magnetic anisotropy. Structural analyses revealed that both complexes contain a peroxide anion‐aggregated triangular {Ln3(μ3...
Three copper(II) coordination polymers (CuCPs), namely, [Cu0.5(1,4‐bib)(SO4)0.5]n (1), {[Cu(1,3‐bib)2(H2O)]·SO4·H2O}n (2), and [Cu(bpz)(SO4)0.5]n (3), were assembled from the reaction of three N‐donors [1,4‐bib = 1,4‐bis(1H‐imidazol‐4‐yl)benzene, 1,3‐bib = 1,3‐bis(1H‐imidazol‐4‐yl)benzene, and Hbpz = 3‐(2‐pyridyl)pyrazole] with copper sulfate under hydrothermal conditions. Their structures were determined...
The coordination polymers [Cd2(bbmb)2(L1)(HL1)0.5(H2O)]n (1), [Cd2(bbmb)2(L2)2(H2O)·(H2O)]n (2), and [Ni(bbmb)2(L3)]n (3), were synthesized by the hydrothermal reaction of 4,4′‐bis(benzimidazol‐1‐ylmethyl)biphenyl (bbmb) with CdII/NiII ions in the presence of three flexible aliphatic acids [tricarballylic acid (H3L1), succinate (H2L2), and adipate (H2L3)]. Complexes 1–3 were structurally characterized...