Search results for: Li‐Yu Ting
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Atomic Ag cluster bonding is employed to reinforce the interface between PF3T nano‐cluster and TiO2 nanoparticle. With an optimized Ag loading (Ag/TiO2 = 0.5 wt%), the Ag atoms will uniformly disperse on TiO2 thus generating a high density of intermediate states in the band gap to form the electron channel between the terthiophene group of PF3T and the TiO2 in the hybrid composite (denoted as T@Ag05‐P)...
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Covalent organic frameworks (COFs), which have layered stacking structures, extended π‐conjugation, and periodic frameworks have become a promising class of materials for a wide range of applications. However, their synthetic pathways frequently need high temperatures, enclosed systems under high pressures, an inert atmosphere, and extended reaction time, which restrict their practicality in real‐world...
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European Journal of Inorganic Chemistry > 27 > 5 > n/a - n/a
The Front Cover demonstrates the photoluminescence phenomenon in a large single crystal of [BnMIm]4[MnBr4]Br2. Bright green emission of the prepared material is achieved through rational structural design, which involves lowering the concentration of [MnBr4]2− tetrahedra (shown in dark green) in the crystal structure to reduce non‐radiative relaxation and increasing the crystallinity of the material...
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European Journal of Inorganic Chemistry > 27 > 5 > n/a - n/a
Ten ionic manganese(II) complexes of [EMIm]2[MnX2Y2] (EMIm=1‐ethyl‐3‐methylimidazolium ion; X, Y=Cl, Br or I) and [BnMIm]2[MnX2Y2] (BnMIm=1‐benzyl‐3‐methylimidazolium ion; X, Y=Cl, Br or I) types were synthesized and studied in terms of their thermal and photophysical properties. Complexes with [BnMIm]+ cation were found to exhibit higher crystallinity, owing to the aromatic π‐stacking, and superior...
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Converting solar energy into hydrogen energy using conjugated polymers (CP) is a promising solution to the energy crisis. Improving water solubility plays one of the critical factors in enhancing the hydrogen evolution rate (HER) of CP photocatalysts. In this study, a novel concept of incorporating hydrophilic side chains to connect the backbones of CPs to improve their HER is proposed. This concept...
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Conjugated polymers (CPs) have recently gained increasing attention as photocatalysts for sunlight‐driven hydrogen evolution. However, they suffer from insufficient electron output sites and poor solubility in organic solvents, severely limiting their photocatalytic performance and applicability. Herein, solution‐processable all–acceptor (A1–A2)‐type CPs based on sulfide‐oxidized ladder‐type heteroarene...
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A hybrid composite of organic–inorganic semiconductor nanomaterials with atomic Au clusters at the interface decoration (denoted as PF3T@Au‐TiO2) is developed for visible–light‐driven H2 production via direct water splitting. With a strong electron coupling between the terthiophene groups, Au atoms and the oxygen atoms at the heterogeneous interface, significant electron injection from the PF3T to...
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